In the above tileset I have created rules for all the possible combinations but I am unable to create rules for the highlighted tile, basically if there is nothing around I want the highlighted tile to show
These tiles must be placed manually, as there is no distinction between them and solid tiles.
You can mark them as equivalent to an all-blue tile (since functionally, they are - all blue on all edges/corners) so that the Terrain tool is aware of them, and set their tile probability to 0 so that they’re not placed automatically where you’d normally want the solid blue tile.